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- 什么是pH标度?
- 点击次数:3157 更新时间:2011-04-24
- pH测量是一种相对测量,实际测量前,需要用标准缓冲溶液进行校准。因此,为了达到量值的一致,必须建立pH标度。水溶液pH标度范围定为(0~14)pH。pH标度的量值由标准缓冲溶液的pHs值确定。因此,pH标度的含义可表达为:根据pH定义,在(0~14)pH范围内选择若干个pH缓冲溶液作为pH标度的固定点,并且采用当代技术能达到的zui准确的方法测定它们的pHS值。上有二种pH标度,即多种基准pH标度和单种基准pH标度,JJG 119-2005公布中六种基准缓冲溶液(0~95)℃的pHs值见表(1)。表(1) 六种基准缓冲溶液的pHs值温度,℃B1B3B4B6B9B1201.668----4.0066.9819.45813.41651.669----3.9996.9499.39113.210101.671----3.9966.9219.33013.011151.673----3.9966.8989.27612.820201.676----3.9986.8799.22612.637251.6803.5594.0036.8649.18212.460301.6843.5514.0106.8529.14212.292351.6883.5474.0196.8449.10512.130401.6943.5474.0296.8389.07211.975451.7003.5504.0426.8349.04211.828501.7063.5554.0556.8339.01511.697551.7133.5634.0706.8348.99011.553601.7213.5734.0876.8378.96811.426701.7393.5964.1226.8478.926----801.7593.6224.1616.8628.890----901.7823.6484.2036.8818.856----951.7953.6604.2246.8918.839----